From Homochiral Assembly to Heterochiral Assem- bly: A Leap in ...
This diamagnetic correction is unique to each system based on ligand and metal, and is here approximated with Equation 418 due to the redox non-innocent ligands.
comprehensive supramolecular chemistry iiThèse dirigée par Sylvie FOUCAUD et co-encadrée par Romain LUCAS et Yann LECONTE. JURY : Présidente du Jury. Claire PEYRATOUT, Professeur. Metal Organic Polygons and Polyhedra: Instabilities and RemediesFor example, Leigh has reported a [2]rotaxane-based catalyst with switchable enantioselectivity (Figure 1.8b).29 Upon irradiation, isomerization of the acyl ... Elaboration des composites SiC/ZrC par synthèse organométallique ...between helicates, tetrahedral and pentagonal prisms, based on labile imine and metal-ligand coordination bonds, again requiring use of a chemical trigger ... Synthesis of Singly Threaded High-order Rotaxanes and ...ABSTRACT. Transition metal-catalyzed reactions find applications in many industrial processes, most commonly using precious-metals. Supramolecular Architectures with Functionalised Host LigandsThe most common and successful design principle used in the synthesis of discrete metal-organic 2D and 3D structures (i.e., metallocycles and ... Nickel Complexes of Diphosphine Ketone and Imine ... - DSpacepublished use of larger, NDI-based ligands that formed octahedral cages, as the rigidity presumably disfavoured the formation of M4L4 complexes [43,44]. The ... CM_u1897814_PhD thesis_13.12.2022_final versionWhat is clear is that these coinage metal-based catalysts are active for a wide variety of borylation reactions, but the mechanistic details of many of the ... Supramolecular Chemistry in the 3rd Millennium - edocThis thesis contains published work and/or work prepared for publication, some of which has been co- authored. The bibliographic details of the works and ... Organometallic Chemistry Volume 34Les travaux réalisés dans cette thèse ont été effectués au Laboratoire de Chimie Inorganique. Appliquée (LCIA), de l'Université de Yaoundé 1 sous la ... Polymerisable Metallomonomers and Multi-Cage Complexes(NDI) and 1,8-diazabicyclo [5.4.0] undec-7-ene (DBU) in one step ... Based on Bipyridyl Metal Complexes. Acc. Chem. Res. 2005, 38 (9) ... INTRODUTION GENERALE - DICAMESThe complexation of the neutral ligand with two equivalents of Ni0 caused the NDI ligand to be reduced by two electrons, while the two Ni0 centers were oxidized ... Synthesis and characterization of photo-activatable systemspublished use of larger, NDI-based ligands that formed octahedral cages, as the rigidity presumably disfavoured the formation of M4L4 complexes [43,44]. The ...
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